Sch. II
PERMISSIBLE LEVELS OF CERTAIN CHEMICAL SUBSTANCES IN WORK ENVIRONMENT.
THE SECOND SCHEDULE
[See section 41F]
PERMISSIBLE LEVELS OF CERTAIN CHEMICAL SUBSTANCES IN WORK ENVIRONMENT
|
Sl.
No.
|
Substance
|
Permissible
limits of exposure
|
|||
|
r
|
e
|
Time-Weighted average concentration (TWA) |
(TWA)
|
Short-term exposure limit (15 min.)
|
(STEL)
|
|
a
|
a
|
PPm
|
mg/m3
|
PPm
|
mg/m3
|
|
1
|
2
|
3
|
4
|
5
|
6
|
|
1
|
Acetaldehyde
|
100
|
180
|
150
|
270
|
|
2
|
Acetic
Acid
|
10
|
25
|
15
|
37
|
|
3
|
Acetone
|
750
|
1780
|
1000
|
2375
|
|
4
|
Acrolein
|
01
|
0.25
|
0.3
|
0.8
|
|
5
|
Acrylonitrile-skin
(S.C)
|
2
|
4.5
|
-
|
-
|
|
6
|
Aldrin-skin
|
-
|
0.25
|
-
|
-
|
|
7
|
Allyl
Chloride
|
1
|
3
|
2
|
6
|
|
8
|
Ammonia
|
0.25
|
18
|
35
|
27
|
|
9
|
Aniline-skin
|
2
|
10
|
-
|
-
|
|
10
|
Anisidine
(O.P.isomers)-skin
|
0.1
|
0.5
|
-
|
-
|
|
11
|
Arsenic
& Soluble compounds (as As)
|
-
|
0.2
|
-
|
-
|
|
12
|
Benzene
(S.C)
|
10
|
30
|
-
|
-
|
|
13
|
Beryllium
& Compounds (as Be) (S.C)
|
-
|
0.002
|
-
|
-
|
|
14
|
Boron
trifluoride C
|
1
|
3
|
-
|
-
|
|
15
|
Bromine
|
0.1
|
0.7
|
0.3
|
2
|
|
16
|
Butane
|
800
|
1900
|
-
|
-
|
|
17
|
2-Butanone
(Methyle ethyle Ketone MEK)
|
200
|
590
|
300
|
885
|
|
18
|
N-Butyl
acetate
|
150
|
710
|
200
|
950
|
|
19
|
N-Butyl
alcohol-skin-C
|
50
|
150
|
-
|
-
|
|
20
|
Sce/tert,
Butyl acetate
|
200
|
950
|
-
|
-
|
|
21
|
Butyl Mercaptan
|
0.5
|
1.5
|
-
|
-
|
|
22
|
Cadmium-dust
and salts (as Cd)
|
-
|
0.05
|
-
|
-
|
|
23
|
Calcium
oxide
|
-
|
2
|
-
|
-
|
|
24
|
Carbaryl
(Sevin)
|
-
|
5
|
-
|
-
|
|
25
|
Carbofuran
(Furadan)
|
-
|
0.1
|
-
|
-
|
|
26
|
Carbon
disulphide-skin
|
10
|
30
|
-
|
-
|
|
27
|
Carbon
monoxide
|
50
|
55
|
400
|
440
|
|
28
|
Carbon tetrachloride-skin (S.C.)
|
5
|
30
|
-
|
-
|
|
29
|
Chlordane-skin
|
-
|
0.5
|
-
|
2
|
|
30
|
Chlorine
|
1
|
3
|
3
|
9
|
|
31
|
Chlorobenzene
(monochlorobenzene)
|
75
|
350
|
-
|
-
|
|
32
|
Chloroform
(S.C.)
|
10
|
50
|
-
|
-
|
|
33
|
bis-(Chloromethyl)
ether (H.C.)
|
0.001
|
0.005
|
-
|
-
|
|
34
|
Chromic
acid and chromates (as Cr) (Water soluble)
|
-
|
0.05
|
-
|
-
|
|
35
|
Chromous
Salts (as Cr)
|
-
|
0.5
|
-
|
-
|
|
36
|
Copper
fume
|
-
|
0.2
|
-
|
-
|
|
37
|
Cotton
dust, raw
|
-
|
0.2
|
-
|
-
|
|
38
|
Cresoal,
all isomers-skin
|
5
|
22
|
-
|
-
|
|
39
|
Cyanides (as Cn)-skin
|
-
|
5
|
-
|
-
|
|
40
|
Cyanogen
|
10
|
20
|
-
|
-
|
|
41
|
DDT
(Dichlorodiphenyl Trichloroethane)
|
-
|
1
|
-
|
-
|
|
42
|
Demeton-skin
|
0.01
|
0.1
|
-
|
-
|
|
43
|
Diazinon-skin
|
-
|
0.1
|
-
|
-
|
|
44
|
Dibutyl Phythalate
|
-
|
5
|
-
|
-
|
|
45
|
Dichlorous
(DDVP)-skin
|
-
|
1
|
-
|
-
|
|
46
|
Dieldrin-skin
|
-
|
0.25
|
-
|
-
|
|
47
|
Dinitrobenzene
(all isomers)-skin
|
0.15
|
1
|
-
|
-
|
|
48
|
Dinitrotoluene-skin
|
-
|
1.5
|
-
|
-
|
|
49
|
Diphenyl
(Biphenyl)
|
0.2
|
1.5
|
-
|
-
|
|
50
|
Endosulfan
(Thiodan)- skin
|
-
|
0.1
|
-
|
-
|
|
51
|
Endrin-skin
|
-
|
0.1
|
-
|
-
|
|
52
|
Ethyl acetate
|
400
|
1400
|
-
|
-
|
|
53
|
Ethyl alcohol
|
1000
|
1900
|
-
|
-
|
|
54
|
Ethylamin
|
10
|
18
|
-
|
-
|
|
55
|
Fluorides (as F)
|
-
|
2.5
|
-
|
-
|
|
56
|
Fluorine
|
1
|
2
|
2
|
4
|
|
57
|
Formaldehyde
(S.C.)
|
1.0
|
1.5
|
2
|
3
|
|
58
|
Formic Acid
|
5
|
9
|
-
|
-
|
|
59
|
Gasoline
|
300
|
900
|
500
|
1500
|
|
60
|
Hydrazine-skin
(S.C.)
|
0.1
|
0.1
|
-
|
-
|
|
61
|
Hydrogen
Chloride-C
|
5
|
7
|
a
|
a
|
|
62
|
Hydrogen Cyanide skin-C
|
10
|
10
|
-
|
-
|
|
63
|
Hydrogen
Fluoride (as F)-C
|
3
|
2.5
|
-
|
-
|
|
64
|
Hydrogen
Peroxide
|
1
|
1.5
|
-
|
-
|
|
65
|
Hydrogen
Sulphide
|
10
|
14
|
15
|
21
|
|
66
|
Iodine-C
|
0.1
|
1
|
-
|
-
|
|
67
|
Iron
Oxide Fume (F0203) (as Fe)
|
-
|
5
|
-
|
-
|
|
68
|
Isoamyl
acetate
|
100
|
525
|
-
|
-
|
|
69
|
Isoamyl
alcohol
|
100
|
360
|
125
|
450
|
|
70
|
Isobutyl
alcohol
|
50
|
150
|
-
|
-
|
|
71
|
Lead,
inorg, dusts, dusts and fumes (as Pb)
|
-
|
0.15
|
-
|
-
|
|
72
|
Lindane-skin
|
-
|
0.5
|
-
|
-
|
|
73
|
Malathion-skin
|
-
|
10
|
-
|
-
|
|
74
|
Manganese
dust and compounds (as (Mn)-C
|
-
|
5
|
-
|
-
|
|
75
|
Manganese
Fume (as Mn)
|
-
|
1
|
-
|
3
|
|
76
|
Mercury
(as Hg)-skin
|
a
|
a
|
a
|
a
|
|
a
|
(i)
Alkyle compounds
|
-
|
0.01
|
-
|
0.03
|
|
a
|
(ii)
All forms except alkyle vapour
|
-
|
0.05
|
-
|
-
|
|
a
|
(iii)
Aryle and inorganic compounds
|
-
|
0.1
|
-
|
-
|
|
77
|
Methyl
alcohol (Methanol)-skin
|
200
|
260
|
250
|
310
|
|
78
|
Methyl
cellosolve (2-methoxyethanol)-skin
|
5
|
16
|
-
|
-
|
|
79
|
Methyl
isobutyl Ketone
|
50
|
205
|
75
|
300
|
|
80
|
Methyl Isocyanate-skin
|
0.02
|
0.05
|
-
|
-
|
|
81
|
Naphthalene
|
10
|
50
|
15
|
75
|
|
82
|
Nickel
carbonyl (as Ni)
|
0.05
|
0.35
|
-
|
-
|
|
83
|
Nitric
acid
|
2
|
5
|
4
|
10
|
|
84
|
Nitric
Oxide
|
25
|
30
|
-
|
-
|
|
85
|
Nitrobenzene-skin
|
1
|
5
|
-
|
-
|
|
86
|
Nitrogen
dioxide
|
3
|
6
|
5
|
10
|
|
87
|
Oil
mist mineral
|
-
|
5
|
-
|
10
|
|
88
|
Ozone
|
0.1
|
0.2
|
0.3
|
0.6
|
|
89
|
Parathion-skin
|
-
|
0.1
|
-
|
-
|
|
90
|
Phenol-skin
|
5
|
19
|
a
|
a
|
|
91
|
Phorate
(Thimet)-skin
|
-
|
0.05
|
0.2
|
-
|
|
92
|
Phosgene (Carbonyl Chloride)
|
0.1
|
0.4
|
-
|
-
|
|
93
|
Phosphine
|
0.3
|
0.4
|
1
|
1
|
|
94
|
Phosphoric acid
|
-
|
1
|
-
|
3
|
|
95
|
Phosphorus
(yellow)
|
-
|
0.1
|
-
|
-
|
|
96
|
Phosphorus
penta- chloride
|
0.1
|
1
|
-
|
-
|
|
97
|
Phosphorus
trichloride
|
0.2 |
1.5
|
0.5
|
3
|
|
98
|
Picric acid-skin
|
-
|
0.1
|
-
|
0.3 |
|
99
|
Pyridine
|
5
|
15
|
-
|
-
|
|
100
|
Silans
(silicon tetrahydride)
|
5
|
7
|
-
|
-
|
|
101
|
Sodium
hydroxide-C
|
-
|
2
|
-
|
-
|
|
102
|
Styrene,
monomer (phanylethlene)
|
50
|
215
|
100
|
425
|
|
103
|
Sulphur
dioxide
|
2
|
5
|
5
|
10
|
|
104
|
Sulphur
hexafluoride
|
1000
|
6000
|
-
|
-
|
|
105
|
Sulphuric
acid
|
-
|
1
|
-
|
-
|
|
106
|
Tetraethyl
lead (as Pb) - Skin
|
-
|
0.1
|
-
|
-
|
|
107
|
Toluene
(Toluol)
|
100
|
375
|
150
|
560
|
|
108
|
O-Toluidine-skin
(S.C.)
|
2
|
9
|
-
|
-
|
|
109
|
Tributylphosohate
|
0.2
|
2.5
|
-
|
-
|
|
110
|
Trichloroethylene
|
50
|
270
|
200
|
1080
|
|
111
|
Uranium
natural (as U)
|
-
|
0.2
|
-
|
0.6
|
|
112
|
Vinyl
Chloride (H.C.)
|
5
|
10
|
-
|
-
|
|
113
|
Welding
fumes
|
-
|
5
|
-
|
-
|
|
114
|
Xylene
(O-m-P-isomers)
|
100
|
435
|
150
|
655
|
|
115
|
Zinc
oxide
|
d
|
a
|
a
|
a
|
|
f
|
(i)
Fume
|
-
|
5.0
|
-
|
10
|
|
d
|
(ii)
Dust (Total dust)
|
-
|
10.00
|
-
|
-
|
|
116
|
Zirconium
compounds (as Zr)
|
-
|
5
|
-
|
10
|